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ABSTRACT
Cationic reverse flotation of kaolinite from bauxite is an alternative to adequate high silica bauxites to the specifications of the Bayer process. However, the presence of clay minerals influences the slurries rheology decreasing the flotation performance. The objective of this work was to investigate the use of ultrasonic pre-treatment on kaolinite flotation and contrast it with the traditionally used chemical dispersant. Two bauxite samples were characterized in terms of chemical and mineralogical composition, as well as particle size distribution. Flotation was accomplished after conditioning with sodium polyacrylate and/or pre-treatment in ultrasound. Determinations of viscosity, sedimentation yield, and screening followed by the analysis of available alumina and reactive silica were also conducted. By increasing the concentration of solids to more than 20 wt.%, the slurry behavior changed from a Newtonian to a non-Newtonian behavior, the viscosity increased, and the flotation performance decreased. The use of chemical dispersant and ultrasonic pre-treatment increased the flotation performance. The ultrasound had a more marked effect in slurries with higher concentrations of solids. This result is related to the synergic effect of particle dispersion and reduction of the slime coating promoted by kaolinite onto gibbsite particles.
Acknowledgments
We are grateful to the Mineral Processing Research Group (Grupo de Pesquisa em Processamento Mineral – GPPM) and to the Postgraduate Program in Chemical Engineering of the Federal University of Alfenas, Minas Gerais State, Brazil, in which the work was developed. Thanks to Alcoa Inc. which sponsored the project.
Disclosure statement
No potential conflict of interest was reported by the author(s).