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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 30, 2000 - Issue 13
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Original Articles

Chemoselective Transfer Hydrogenation of Carbonyl Compounds Catalyzed by Macrocyclic Nickel (II)Complex

Prodeep Phukan Process Development Division National Chemical Laboratory, Pune, 411 008, INDIA
&
A. Sudalai Process Development Division National Chemical Laboratory, Pune, 411 008, INDIA
Pages 2401-2405 | Received 16 Aug 1999, Published online: 04 Dec 2007
 
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Abstract

Macrocyclic Ni(II) complex, 1, catalyzes efficiently the chemoselective transfer reduction of carbonyl compounds in presence of propan-2-ol / KOH or HCO2H / HCO2NH4 as hydrogen donors to produce the corresponding alcohols in high yield.

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