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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 30, 2000 - Issue 17
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Original Articles

Potassium Exchanged Layered Zirconium Phosphate as Base Catalyst for the Desilylation of Phenol Silyl Ethers

Massimo Curini Istituto di Chimica Organica, Facoltà di Farmacia, Università degli Studi, Via del Liceo, I-06123, Perugia, Italy
,
Francesco Epifano Istituto di Chimica Organica, Facoltà di Farmacia, Università degli Studi, Via del Liceo, I-06123, Perugia, Italy
,
Maria Carla Marcotullio Istituto di Chimica Organica, Facoltà di Farmacia, Università degli Studi, Via del Liceo, I-06123, Perugia, Italy
,
Ornelio Rosati Istituto di Chimica Organica, Facoltà di Farmacia, Università degli Studi, Via del Liceo, I-06123, Perugia, Italy
,
Monia Rossi Istituto di Chimica Organica, Facoltà di Farmacia, Università degli Studi, Via del Liceo, I-06123, Perugia, Italy
&
André Tsadjout Istituto di Chimica Organica, Facoltà di Farmacia, Università degli Studi, Via del Liceo, I-06123, Perugia, Italy
Pages 3181-3187 | Received 08 Dec 1999, Published online: 04 Dec 2007
 
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Abstract

Layered zirconium hydrogen phosphonate exchanged with the potassium ion was found to be an efficient heterogeneous catalyst for the hydrolysis of sterically hindered phenolic silyl ethers.

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