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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 30, 2000 - Issue 22
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Original Articles

Clay Catalysed Convenient Isomerization of Natural Furofuran Lignans Under Microwave Irradiation

Biswanath Das Organic Chemistry Division-I, Indian Institute of Chemical Technology, Hyderabad, 500 007, India
,
P. Madhusudhan Organic Chemistry Division-I, Indian Institute of Chemical Technology, Hyderabad, 500 007, India
&
B. Venkataiah Organic Chemistry Division-I, Indian Institute of Chemical Technology, Hyderabad, 500 007, India
Pages 4001-4006 | Received 30 Jan 2000, Published online: 04 Dec 2007
 
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Abstract

The naturally occuring furofuron lignans, (+)-sesamin, (+)-eudesmin, (+)-syringaresinol and (+)-yangambin underwent rapid isomerization to their corresponding C-7 epimers under microwave irradiation in the presence of montmorillonite KSF as catalyst.

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