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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 30, 2000 - Issue 10
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Original Articles

Stereoselective Synthesis of E-Vinyltellurides by the Reaction of Vinylic Zirconium with ArTeTeAr

Xian Huang Department of Chemistry, Zhejiang University, (Campus Xixi), 34 Tianmushanlu, Hangzhou, 310028, P.R. China
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Chun-Gen Liang Department of Chemistry, Zhejiang University, (Campus Xixi), 34 Tianmushanlu, Hangzhou, 310028, P.R. China
Pages 1737-1741 | Accepted 01 Aug 1999, Published online: 04 Dec 2007
 
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Abstract

1-Alkynes react with Cp2Zr(H)Cl (Cp= η-C5H5) giving vinylzirconium complexes, which are trapped with diarylditellurides to afford (E)-vinylic tellurides.

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