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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 30, 2000 - Issue 10
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Original Articles

The Application of Ceric Ammonium Nitrate in the Synthesis of Carbodiazones

Jun-Ping Xiao Department of Chemistry, Henan Normal University, Xinxiang, 453002, P. R. China
,
Yu-Lu Wang Department of Chemistry, Henan Normal University, Xinxiang, 453002, P. R. China
,
Xue-Shun Jia Department of Chemistry, Henan Normal University, Xinxiang, 453002, P. R. China
,
Xiao-Yang Wang Department of Chemistry, Henan Normal University, Xinxiang, 453002, P. R. China
&
Hong Wang Department of Chemistry, Henan Normal University, Xinxiang, 453002, P. R. China
Pages 1807-1812 | Accepted 27 Aug 1999, Published online: 04 Dec 2007
 
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Abstract

The preparation of bisaryl carbodiazone compounds from the aryl substituted carbazides with Ceric Ammonium Nitrate (CAN) has been reported for the first time in excellent yields (80-91%). This method only needs simple instruments and short reaction time. A possible mechanism has been suggested.

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