Synthesis of 2t-Substituted-1r,3c-BIS(2′-Hydroxy-5-Substituted-Benzyl)-Imidazolidines by Reaction of 1,3-BIS(2′-Hydroxy-5′-Substituted-Benzyl)-Imidazolidines with Aromatic Aldehydes

Augusto Rivera Departamento de Química, Universidad Nacional de Colombia, Ciudad Universitaria, A.A. 14490, Santafé de Bogotá, D.C., Colombia

Juan Francisco León Departamento de Química, Universidad Nacional de Colombia, Ciudad Universitaria, A.A. 14490, Santafé de Bogotá, D.C., Colombia

Jasmin Rivera Departamento de Química, Universidad Nacional de Colombia, Ciudad Universitaria, A.A. 14490, Santafé de Bogotá, D.C., Colombia

Eva Cecilia Parra Departamento de Química, Universidad Nacional de Colombia, Ciudad Universitaria, A.A. 14490, Santafé de Bogotá, D.C., Colombia

Jindra Purmova Departamento de Química, Universidad Nacional de Colombia, Ciudad Universitaria, A.A. 14490, Santafé de Bogotá, D.C., Colombia

Eleuterio Burgueño-Tapia Departamento de Química, Centro de Investigación y de Estudios Avanzados, Instituto Politécnico Nacional, Apartado 14-740, México, D.F., 07000, México

Pedro Joseph-Nathan Departamento de Química, Centro de Investigación y de Estudios Avanzados, Instituto Politécnico Nacional, Apartado 14-740, México, D.F., 07000, México

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Abstract

A one-step synthesis of 2t-substituted-1r,3c-bis(2′-hydroxy-5′- substituted-benzyl)-imidazolidines from 1,3-bis(2′-hydroxy-5′-substituted-benzyl)-imidazolidines and aromatic aldehydes is reported. The relative stereochemistry of the five-membered ring was evident from ¹H NMR measurements combined with MMX calculations.

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Synthesis of 2t-Substituted-1r,3c-BIS(2′-Hydroxy-5-Substituted-Benzyl)-Imidazolidines by Reaction of 1,3-BIS(2′-Hydroxy-5′-Substituted-Benzyl)-Imidazolidines with Aromatic Aldehydes

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Synthesis of 2t-Substituted-1r,3c-BIS(2′-Hydroxy-5-Substituted-Benzyl)-Imidazolidines by Reaction of 1,3-BIS(2′-Hydroxy-5′-Substituted-Benzyl)-Imidazolidines with Aromatic Aldehydes

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