Stereoselective Conjugate Additions of Alcohols to a Chiral (E)-Nitroalkene Derived From (R)-2,3-Isopropylidene Glyceraldehyde

Qian Cheng Laboratory of Applied Bioorganic Chemistry, Division of Life Science Graduate School of Agricultural Science, Tohoku University 1--1 Tsutsumidori-Amamaiyamachi, Aoba-ku, Sendai, 981--8555, Japan

Takayuki Oritani Laboratory of Applied Bioorganic Chemistry, Division of Life Science Graduate School of Agricultural Science, Tohoku University 1--1 Tsutsumidori-Amamaiyamachi, Aoba-ku, Sendai, 981--8555, Japan

Alfred Hassner Department of Chemistry, Bar-Ilan University, Ramat-Gan, 52900, Israel

Abstract

Addition of functionalized alcohols to a chiral (E)-nitroalkene proceeded with modest to high diastereoselectivities depending on the presence of metal catalysts in low temperature. The results indicated that anti-selectivities were preferred in all cases.

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Stereoselective Conjugate Additions of Alcohols to a Chiral (E)-Nitroalkene Derived From (R)-2,3-Isopropylidene Glyceraldehyde

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Stereoselective Conjugate Additions of Alcohols to a Chiral (E)-Nitroalkene Derived From (R)-2,3-Isopropylidene Glyceraldehyde

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