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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 30, 2000 - Issue 2
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Original Articles

A Convenient and Stereoselective Synthesis of (E)-Vinylic Selenides

Xian Huang Department of Chemistry, Zhejiang University(Campus Xixi), Hangzhou, 310028, P.R., China
&
Jun-Hua Wang Department of Chemistry, Zhejiang University(Campus Xixi), Hangzhou, 310028, P.R., China
Pages 307-312 | Received 15 Feb 1999, Published online: 04 Dec 2007
 
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Abstract

The insertion of elemental selenium into the Csp2-Zr bond of alkenylchlorozirconocenes affords (E)-vinylseleno zirconocenes, which were trapped by alkyl halides giving (E)-vinylic selenides in moderate to good yields.

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