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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 30, 2000 - Issue 14
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Original Articles

Highly Selective Synthesis of Acetylenic Alcohols Promoted by Metallic Dysprosium in the Presence of Mercuric Chloride

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Pages 2515-2524 | Received 15 Jun 1999, Published online: 04 Dec 2007
 

Abstract

Promoted by metallic dysprosium, carbonyl compounds react smoothly with propargyl bromide to afford the corresponding homopropargylic alcohols in good to excellent yields without observation of allenic alcohols. In addition, this reaction is regioselective and chemoselective.

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