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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 30, 2000 - Issue 14
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Original Articles

Studies in Competitive [3,3] Sigmatropic Rearrangement: Synthesis of Oxygen Heterocycles

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Pages 2613-2623 | Received 19 Oct 1999, Published online: 04 Dec 2007
 

Abstract

[3,3] Sigmatropic rearrangement of unsymmetrically substituted 1,4-but-2-ynes exhibit preference for rearrangement on the aryloxy prop-2-ynyl moiety to N-methyl-N-pyrimidinyl amino prop-2-ynyl moiety in case of 5-substituted uracils (la-f).

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