Synthesis of 3‐Alkyl and Arylapomorphines

Attila Sipos Department of Organic Chemistry, University of Debrecen, Debrecen, Hungary

Szilvia Debreceni Department of Organic Chemistry, University of Debrecen, Debrecen, Hungary

Renáta Szabó Department of Organic Chemistry, University of Debrecen, Debrecen, Hungary

Zsuzsanna Gyulai Department of Organic Chemistry, University of Debrecen, Debrecen, Hungary

Sándor Berényi Department of Organic Chemistry, University of Debrecen, Debrecen, HungaryCorrespondence[email protected]

Abstract

The synthesis of 3‐alkyl and arylapomorphines 18–20 has been accomplished by using the Suzuki–Miyaura cross‐coupling reaction of vinyl‐ and allylhalide morphinanedienes or arylhalide apocodeines and arylboronic acids.

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Acknowledgments

The authors are grateful for the substantial discussion with Sándor Antus and for the financial support from the National Science Foundation (Grant OTKA Reg. Nos. T049436 and NI61336).

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Synthesis of 3‐Alkyl and Arylapomorphines

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Synthesis of 3‐Alkyl and Arylapomorphines

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