Samarium Triiodide–Catalyzed Formation of Mannich‐Type Products by Amidoalkylation of 1,3‐Dicarbonyl Compounds

Xiaoxia Wang Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces, College of Chemistry and Life Sciences, Zhejiang Normal University, Jinhua, China E-mail: [email protected]Correspondence[email protected]

Hui Mao Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces, College of Chemistry and Life Sciences, Zhejiang Normal University, Jinhua, China E-mail: [email protected]

Yan Yu Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces, College of Chemistry and Life Sciences, Zhejiang Normal University, Jinhua, China E-mail: [email protected]

Xiudan Zhu Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces, College of Chemistry and Life Sciences, Zhejiang Normal University, Jinhua, China E-mail: [email protected]

Chunlan Zhu Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces, College of Chemistry and Life Sciences, Zhejiang Normal University, Jinhua, China E-mail: [email protected]

Abstract

With samarium triiodide (SmI₃) as a catalyst, the amidoalkylation of 1,3‐dicarbonyl compounds with N‐(1‐benzotriazol‐1‐ylalkyl)amides proceeded readily under mild conditions to afford Mannich‐type products in good to excellent yields.

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Acknowledgments

We are grateful to the Natural Science Foundation of Zhejiang Province (Project No. Y405035) for financial support.

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Samarium Triiodide–Catalyzed Formation of Mannich‐Type Products by Amidoalkylation of 1,3‐Dicarbonyl Compounds

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Samarium Triiodide–Catalyzed Formation of Mannich‐Type Products by Amidoalkylation of 1,3‐Dicarbonyl Compounds

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