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Ethylbenzonitriles were synthesized by selective gas-phase ammoxidation of ethylbenzyl chlorides prepared by chloromethylation of ethylbenzene in good yields and almost 100% selectivity at ca. 200 °C for the first time.
The authors are grateful for the financial support from the Natural Sciences Foundation of China (40830852, 21172269) and the Natural Sciences Foundation of Hubei Province (2008CDZ038).
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