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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 42, 2012 - Issue 7
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Original Articles

Synthesis, X-Ray Analysis, and Evaluation of the Optoelectronic Properties of a New Thia[6]helicene

, , &
Pages 1010-1018 | Received 27 Sep 2010, Published online: 16 Dec 2011
 

Abstract

The synthesis and structural characterization of a new hexahelicene derivative is reported. This compound features a new type of structure bearing a bromine atom. Suitable crystals of the latter indicate that its conformation closely resembles that of the unsubstituted [6]helicene, whose idealized symmetry is C2. The optoelectronic properties of this helical hexacyclic system were determined and exhibit a very interesting behavior.

GRAPHICAL ABSTRACT

ACKNOWLEDGMENT

The authors are grateful to the DGRS (Direction Générale de la Recherche Scientifique) of the Tunisian Ministry of Higher Education and Scientific Research for financial support.

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