Synthetic Communications

An International Journal for Rapid Communication of Synthetic Organic Chemistry

Volume 49, 2019 - Issue 5

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Oxidation of 1,4-disubstituted-1,2,3-triazoles with H₂O₂-CF₃CO₂H: efficient synthesis of 1,2,3-triazole 3-oxides

Norberto González-MojicaCentro Conjunto de Investigación en Química Sustentable UAEM-UNAM, Universidad Autónoma del Estado de México, Toluca, Estado de México, MexicoView further author information

Leticia Almazán-SánchezCentro Conjunto de Investigación en Química Sustentable UAEM-UNAM, Universidad Autónoma del Estado de México, Toluca, Estado de México, MexicoView further author information

Jesús G. García-TorresCentro Conjunto de Investigación en Química Sustentable UAEM-UNAM, Universidad Autónoma del Estado de México, Toluca, Estado de México, MexicoView further author information

Ivette Santana-MartinezCentro Conjunto de Investigación en Química Sustentable UAEM-UNAM, Universidad Autónoma del Estado de México, Toluca, Estado de México, MexicoView further author information

Diego Martínez-OteroCentro Conjunto de Investigación en Química Sustentable UAEM-UNAM, Universidad Autónoma del Estado de México, Toluca, Estado de México, MexicoView further author information

Miguel A. Sánchez-CarmonaCentro Conjunto de Investigación en Química Sustentable UAEM-UNAM, Universidad Autónoma del Estado de México, Toluca, Estado de México, MexicoView further author information

Erick Cuevas-YañezCentro Conjunto de Investigación en Química Sustentable UAEM-UNAM, Universidad Autónoma del Estado de México, Toluca, Estado de México, MexicoCorrespondence[email protected]

http://orcid.org/0000-0002-9437-637X View further author information

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Abstract

A collection of 1,2,3-triazole-3-oxides was obtained from oxidation of the corresponding 1,4-disubstituted-1,2,3-triazoles mediated by a H₂O₂-CF₃CO₂H system through a simple protocol in good yields showing high efficiency.

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Acknowledgments

The authors would like to thank N. Zavala, A. Nuñez, and L. Triana for the technical support.

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Funding

Financial support from SIEA-UAEMEX (Project No. 4326/2017/C1) and CONACYT (Project No. 135053) is gratefully acknowledged.

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Oxidation of 1,4-disubstituted-1,2,3-triazoles with H₂O₂-CF₃CO₂H: efficient synthesis of 1,2,3-triazole 3-oxides

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Oxidation of 1,4-disubstituted-1,2,3-triazoles with H2O2-CF3CO2H: efficient synthesis of 1,2,3-triazole 3-oxides

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Oxidation of 1,4-disubstituted-1,2,3-triazoles with H₂O₂-CF₃CO₂H: efficient synthesis of 1,2,3-triazole 3-oxides