NHC-coordinated palladacycle catalyzed 1,2-addition of arylboronates to unactivated ketones

Ryo AkiyamaDepartment of Materials Science and Engineering, Graduate School of Engineering, Tokyo Denki University, Adachi-ku, Tokyo, Japan; View further author information

Mariko SugayaDepartment of Materials Science and Engineering, Graduate School of Engineering, Tokyo Denki University, Adachi-ku, Tokyo, Japan; View further author information

Hiraku ShinozakiDepartment of Applied Chemistry, School of Engineering, Tokyo Denki University, Adachi-ku, Tokyo, JapanView further author information

Tetsuya YamamotoDepartment of Applied Chemistry, School of Engineering, Tokyo Denki University, Adachi-ku, Tokyo, JapanCorrespondence[email protected]
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Abstract

Palladium catalyzed intermolecular 1,2-addition of arylboronate to unactivated ketone was investigated. NHC-coordinated palladacycle 4c exhibited catalytic activity for the reactions and provided the corresponding tertiary alcohols and γ,γ-disubstituted γ-lactones in good to excellent yields.

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Funding

This work was supported in part by the Research Institute for Science and Technology, Tokyo Denki University Grant Number Q16E-02.

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NHC-coordinated palladacycle catalyzed 1,2-addition of arylboronates to unactivated ketones

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NHC-coordinated palladacycle catalyzed 1,2-addition of arylboronates to unactivated ketones

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