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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 51, 2021 - Issue 17
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Articles

Synthesis of 1,2-diketones by mercury-catalyzed alkyne oxidation

, , , , , & ORCID Icon show all
Pages 2661-2667 | Received 18 Apr 2021, Published online: 30 Jun 2021
 

Abstract

The first mercury-catalyzed synthesis of 1,2-diketones by alkyne oxidation has been developed. This inexpensive method extends the potential of mercury catalysis and allows the rapid construction of various 1,2-diketones and α-carbonyl amides in good yields with high functional group tolerance.

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Funding

This work was supported by the Natural Science Foundation of Zhejiang Province [LQ21B020010], Scientific Research Fund of Zhejiang Provincial Education Department [Y201942345], the Natural Science Foundation of Ningbo [2019A610193], the Zhejiang Provincial Top Key Discipline of Bioengineering [ZS2017014].

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