Acid Catalyzed Reaction of Isocyanide with Epoxide

T. Saegusa Department of Synthetic Chemistry, Kyoto University, Kyoto, Japan

N. Taka-ishi Department of Synthetic Chemistry, Kyoto University, Kyoto, Japan

M. Takami Department of Synthetic Chemistry, Kyoto University, Kyoto, Japan

Y. Ito Department of Synthetic Chemistry, Kyoto University, Kyoto, Japan

Abstract

We have reported the acid–catalyzed cycloadditions of isocyanide with carbonyl compounds^1,2) and with Schiff bases,³⁾ in which the isocyanide component is incorporated as an imine group into the heterocyclic products. The cycloaddition of isocyanide with oxetane, four–membered cyclic ether, has also been realized with the aid of BF₃.Et₂o, which produces 1:1 cyclic adduct of 2–iminoterrahydrofuran.⁴⁾.

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Order Reprints Request Corporate Permissions

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

Request Academic Permissions

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.

Acid Catalyzed Reaction of Isocyanide with Epoxide

Information for

Open access

Opportunities

Help and information

Acid Catalyzed Reaction of Isocyanide with Epoxide

Abstract

Reprints and Corporate Permissions

Academic Permissions

Related research

To cite this article:

Download citation

Information for

Open access

Opportunities

Help and information

Keep up to date

Your download is now in progress and you may close this window

Login or register to access this feature