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In recent years, we have reported on the cycloaddition reactions of dichloroketene to diphenylfulvene1, diphenylbenzorulvene1, and indene2. Last year Kaplan and Hartwig3 published an interesting communication describing the photolysis of exo-3-chlorobicyclo [2.2.1] hept-5-en-2-one (1) to from endo-ó-carbomethoxybicyclo [3.1.0] hex-2-ene (2) in a stereospecific manner.
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