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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 8, 1978 - Issue 4
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Original Articles

Preparation of Hexa-1, 5-Diyne-3-one

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Pages 205-209 | Received 09 Dec 1977, Published online: 06 Dec 2006
 

Abstract

Hexa-1,5-diyne-3-one is a molecule of some potential synthetic utility. We had occasion to prepare this new substance (II) in another context. Although the ketone II can be prepared by the well known chromium trioxide (Jones) oxidation of the alcohol I, the conventional

method of carrying out that oxidation was not successful because of the lability of the product II.

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