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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 11, 1981 - Issue 1
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Original Articles

Bromination of Some Heteroaromatic Acyl Compounds with Aqueous Bromine/Sodium Acetate

Olle Karlsson Division of Organic Chemistry 1, Chemical Center, University of Lund, P.O. Box 740, S-220 07, Lund, 7, Sweden
Pages 29-34 | Published online: 05 Dec 2006
 
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Abstract

Simple acylthiophenes are usually brominated in the side-chain by elemental bromine1,2 due to acid-catalyzed enolization followed by bromination of the enol.3 Nuclear bromination can be achieved by bromine in an excess of aluminium trichloride.4-7

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