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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 11, 1981 - Issue 12
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Original Articles

A Convenient Synthesis of 2-Alkyl-3-Deutero-2-Cyclopropene-1-Carboxylic Acids

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Pages 999-1004 | Published online: 05 Dec 2006
 

Abstract

Cyclopropenes possess very high strain energies1 and their organic and organometallic chemistry has been widely studied. They are reactive dienophiles in the Diels-Alder reaction,2 and they undergo ring opening reactions under vigorous photochemical3 and thermal4 conditions.5 Transition metal promoted ring opening reactions of cyclopropenes occur under very mild conditions,6 and have also been the subject of a theoretical study.7

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