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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 13, 1983 - Issue 14
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Original Articles

Unexpected Solvent Effect of HMPA. Directed Selectivity of a Semistabilized Arsonium Ylide towards Carbonyl Compounds: The Case of Cinnamyl Triphenylarsonate

J. B. Ousset Laboratoire de Stéréochimie de l'Ecole Nationale Supérieure de Chimie (ERA 687), Université Louis Pasteur, 67008, Strasbourg, France
,
C. Mioskowski Laboratoire de Stéréochimie de l'Ecole Nationale Supérieure de Chimie (ERA 687), Université Louis Pasteur, 67008, Strasbourg, France
&
G. Solladié Laboratoire de Stéréochimie de l'Ecole Nationale Supérieure de Chimie (ERA 687), Université Louis Pasteur, 67008, Strasbourg, France
Pages 1193-1196 | Published online: 05 Dec 2006
 
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Abstract

Arsonium ylides have been shown previously1 to react with carbonyl compounds to give either epoxides or alkenes or most of the time a mixture of both depending on the system and the reaction medium.

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