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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 13, 1983 - Issue 13
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Original Articles

Reduction of Aromatic Hydrocarbons by a New Reducing System: Calcium Metal in Amines

Robert A. Benkeser Department of Chemistry, Purdue University, West Lafayette, Indiana, 47907
,
Frank G. Belmente Department of Chemistry, Purdue University, West Lafayette, Indiana, 47907
&
Mei-Hui Yang Department of Chemistry, Purdue University, West Lafayette, Indiana, 47907; Department of Chemistry, National Taiwan University, Taipei, Taiwan
Pages 1103-1116 | Published online: 03 Jan 2007
 
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Abstract

Recently we reported that calcium in an equal volume mixture of methyl ami ne and ethyl enedi ami ne reduces aromatic hydrocarbons to monoal kenes and that for certain substrates unconjugated cyclic dienes are the preferred product.

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