Oxidative Cleavage of Ketoximes with Iodosobenzene Diacetate

Robert M. Moriarty Department of Chemistry, University of Illinois at Chicago, P.O. Box 4348, Chicago, Illinois, 60680

Om Prakash Department of Chemistry, University of Illinois at Chicago, P.O. Box 4348, Chicago, Illinois, 60680

Pushpa R. Vavilikolanu Department of Chemistry, University of Illinois at Chicago, P.O. Box 4348, Chicago, Illinois, 60680

Abstract

Hypervalent iodine oxidation of ketoximes (1) using iodosobenzene diacetate leads to cleavage of 1 with the formation of corresponding ketones (2) under neutral conditions in good yields. The scope and limitations of the reaction are discussed as well as the mechanism.

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Oxidative Cleavage of Ketoximes with Iodosobenzene Diacetate

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Oxidative Cleavage of Ketoximes with Iodosobenzene Diacetate

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