Synthesis of Diarylselenides and Diarylsulfides Under Phase Transfer Conditions

J. [Tacute]ercio Departamento de Química, Universidade Federal de São Carlos Caixa, Postal 676, 13560, São Carlos, SP, BRASIL

B. Ferreira Departamento de Química, Universidade Federal de São Carlos Caixa, Postal 676, 13560, São Carlos, SP, BRASIL

F. Simonelli Departamento de Química, Universidade Federal de São Carlos Caixa, Postal 676, 13560, São Carlos, SP, BRASIL

J. V. Comasseto Instituto de Química, Universidade de São Paulo Caixa, Postal 20.780, 01000, São Paulo, SP, BRASIL

Abstract

Diarylselenides and diarylsulfides are synthesized from the corresponding diaryldiselenide and diaryldisulfide by reduction with aminoiminomethanesulfinic acid, and reaction with activated aryl halides under phase transfer conditions. The reactions yields vary from good to excellent.

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Synthesis of Diarylselenides and Diarylsulfides Under Phase Transfer Conditions

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Synthesis of Diarylselenides and Diarylsulfides Under Phase Transfer Conditions

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