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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 16, 1986 - Issue 14
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Original Articles

Ring Cleavage of Cyclic 2-Nitroketones by KF Catalyst: A General Synthesis of ω-Nitroacids and ω-Nitroesters

Roberto Ballini Dipartimento di Scienze Chimiche Via S.Agostino, 1 62O32, Camerino, Italy
&
Marino Petrini Dipartimento di Scienze Chimiche Via S.Agostino, 1 62O32, Camerino, Italy
Pages 1781-1788 | Published online: 05 Dec 2006
 
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Abstract

Preparation of ω-nitroacids and ω-nitroesters has been achieved by ring cleavage of 2-nitrocycloalkanones, under basic condition (KF), in water (THF solution) or alcohol.

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