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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 16, 1986 - Issue 14
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Original Articles

Studies on the Synthesis of Eremophilane Sesquiterpenes. A Novel Entry into the Aristolane Ring System

James H. Rigby Department of Chemistry, Wayne State University, Detroit, MI, 48202
&
Jean-Pierre Denis Department of Chemistry, Wayne State University, Detroit, MI, 48202
Pages 1789-1798 | Published online: 05 Dec 2006
 
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Abstract

Readily available tricyclo[3.2.2.02,4]non-6-en-8-one is converted into the tricyclo ring system of the aristolane sesquiterpenes via an alkoxide accelerated [3, 3]-sigmatropic rearrangement.

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