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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 16, 1986 - Issue 2
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Original Articles

Ring Enlarging Dipolar Cycloadditions of Chlorosulfonylisocyanate to Epoxides

Tibor Lorincz Department of Chemistry, San Francisco State University, San Francisco, CA, 94132
,
Ihsan Erden Department of Chemistry, San Francisco State University, San Francisco, CA, 94132
,
Reinhard Näder Institut für Organische Chemie der Universität, Martin-Luther-King-Platz 6, 2000, Hamburg 13, W. Germany
&
Armin de Meijere Institut für Organische Chemie der Universität, Martin-Luther-King-Platz 6, 2000, Hamburg 13, W. Germany
Pages 123-130 | Published online: 05 Dec 2006
 
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Abstract

Chlorosulfonyl isocyanate cycloadds to epoxides at -78° to give 1,3-dioxolan-2-ones and/or 2-oxazolidones in moderate yields after aqueous work-up.

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