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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 16, 1986 - Issue 4
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Original Articles

Synthesis of Unsymmetrical 1,4-Diketones Via the Michael-Stetter Reaction

Richard B. Phillips FMC Corporation, Agricultural Chemical Group, Princeton, NJ, 08540
,
Sue A. Herbert FMC Corporation, Agricultural Chemical Group, Princeton, NJ, 08540
&
Albert J. Robichaud FMC Corporation, Agricultural Chemical Group, Princeton, NJ, 08540
Pages 411-417 | Published online: 05 Dec 2006
 
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Abstract

The cyanide catalyzed 1,4-Michael addition of aldehydes to α, β-unsaturated ketones has been examined with regard to substituent effects. Adjustment of the donor/acceptor relationship allows for the synthesis of multisubstituted diaryl 1,4-diketones.

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