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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 16, 1986 - Issue 3
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Original Articles

Diels-Alder Reactions of Cycloalkenones. 8. A One-Step Preparation of 4,4-Dimethyl-1-Octalones, Useful Intermediates in Terpene Synthesis

Francesco Fringuelli Dipartimento di Chimica, Università di Perugia Via Elce di Sotto, 10, 06100, Perugia, Italy
,
Ferdinando Pizzo Dipartimento di Chimica, Università di Perugia Via Elce di Sotto, 10, 06100, Perugia, Italy
,
Aldo Taticchi Dipartimento di Chimica, Università di Perugia Via Elce di Sotto, 10, 06100, Perugia, Italy
&
Ernest Wenkert Department of Chemistry (D-006), University of California-San Diego La Jolla, California, 92093, U.S.A.
Pages 245-249 | Published online: 19 Dec 2006
 
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Abstract

The synthesis of cis- and trans-4,4-dimethyl-1-octalones by acid-catalyzed Diels-Alder reactions of 2-cyclohexenones is reported and the regiochemistry of reactions with isoprene discussed.

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