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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 16, 1986 - Issue 3
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Original Articles

Facile Synthesis of Alkyl 5-Alkoxy-3-Oxopentanoates

Ignacio H. Sánchez Instituto de Química, Universidad, Nacional Autónoma de México, Circuito Exterior, Ciudad Universitaria, Coyoacán, 04510, México, D. F.
,
María Isabel Larraza Instituto de Química, Universidad, Nacional Autónoma de México, Circuito Exterior, Ciudad Universitaria, Coyoacán, 04510, México, D. F.
,
Francisco Kuri Breña Instituto de Química, Universidad, Nacional Autónoma de México, Circuito Exterior, Ciudad Universitaria, Coyoacán, 04510, México, D. F.
,
Adrián Crúz Instituto de Química, Universidad, Nacional Autónoma de México, Circuito Exterior, Ciudad Universitaria, Coyoacán, 04510, México, D. F.
,
Octavio Sotelo Instituto de Química, Universidad, Nacional Autónoma de México, Circuito Exterior, Ciudad Universitaria, Coyoacán, 04510, México, D. F.
&
Humberto J. Floras Instituto de Química, Universidad, Nacional Autónoma de México, Circuito Exterior, Ciudad Universitaria, Coyoacán, 04510, México, D. F.
Pages 299-308 | Published online: 19 Dec 2006
 
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Abstract

A facile synthesis of several alkyl 5-alkoxy-3-oxopentanoates, based on the reductive elimination of triphenylphosphine from the readily available alkyl 5-alkoxy-3-oxo-2-(triphenylphosphoranylide-ne) pentanoates, is described.

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