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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 16, 1986 - Issue 3
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Original Articles

Epoxide Ring Opening by α-Sulfonyl Carbanions. Synthesis of γ-Hydroxy Sulfones and Triflones

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Pages 309-329 | Published online: 19 Dec 2006
 

Abstract

γ-Hydroxy sulfones and triflones are obtained in moderate to excellent yields when n-butyl lithium is added to a mixture of sulfone and epoxide in toluene at 65[ddot] C followed by heating from four to twenty hours at 110[ddot] C.

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