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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 16, 1986 - Issue 5
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Original Articles

Synthesis of trans-Non-4-EN-2-Ynoic Acid

Radoslav Vlahov Institute of Organic Chemistry with Centre of Phytochemistry and Chemistry of Natural Products, Bulgarian Academy of Sciences 1113 Sofia, (Bulgaria)
,
Velichko Tarpanov Institute of Organic Chemistry with Centre of Phytochemistry and Chemistry of Natural Products, Bulgarian Academy of Sciences 1113 Sofia, (Bulgaria)
,
Ioncho Vlahov Institute of Organic Chemistry with Centre of Phytochemistry and Chemistry of Natural Products, Bulgarian Academy of Sciences 1113 Sofia, (Bulgaria)
,
Branimir Milenkov Institute of Organic Chemistry with Centre of Phytochemistry and Chemistry of Natural Products, Bulgarian Academy of Sciences 1113 Sofia, (Bulgaria)
,
Violeta Dacheva Institute of Organic Chemistry with Centre of Phytochemistry and Chemistry of Natural Products, Bulgarian Academy of Sciences 1113 Sofia, (Bulgaria)
&
Günther Snatzke Lehrstuhl für Strukturchemie, Ruhruniversität D-4630 Bochum (FRG)
Pages 509-511 | Published online: 19 Dec 2006
 
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Abstract

The synthesis of the title compound has been achieved from 1 -methoxybutenyne in 77% yield in three steps. A reaction mechanism is given to explain exclusive formation of 4,5-trans-configuration.

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