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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 17, 1987 - Issue 13
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Original Articles

A Facile Procedure for the Synthesis of N-(Tosyl) Imino-2 Acetic Acid Esters, Important Enophiles for the Direct Synthesis of Exotic Alpha-Aminoacids

Michèle Baillargé CNRS-CERCOA 2 à 8, rue Henri Dunant, 94320, Thiais, (France)
&
Francois Le Goffic CNRS-CERCOA 2 à 8, rue Henri Dunant, 94320, Thiais, (France)
Pages 1603-1606 | Published online: 06 Dec 2006
 
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Abstract

Esters of glyoxylic acid and tosylisocyanate react smoothly and afford in a quantitative yield N-tosyl imino-2 acetic acid esters which are key molecules in the ene reaction.

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