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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 17, 1987 - Issue 8
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Original Articles

A Photochemical Approach to the Bicyclo [5.3.1] Undecane Ring System of Taxane Diterpenes

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Pages 913-920 | Published online: 05 Dec 2006
 

Abstract

The bicyclo [5.3.1] undecane derivative 12, an important structural element of the taxane diterpenes, was prepared by photocycloaddition of the bicyclo [3.3.1] dione 9 to allene followed by cyclobutane ring opening (the de Mayo reaction).

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