Hydrogenation of Diaryl and Arylalkyl Ketones by Sodium Borohydride and Aluminum Chloride

Aoi Ono Department of Chemistry, Faculty of Education, Niigata University, Niigata, 950-21, Japan

Tamiko Maruyama Department of Chemistry, Faculty of Education, Niigata University, Niigata, 950-21, Japan

Nobuko Suzuki Department of Chemistry, Faculty of Education, Niigata University, Niigata, 950-21, Japan

Abstract

Diaryl and arylalkyl ketones such as acetophe-none, p-methylacetophenone, propiophenone, and benzophe-none as well as diaryl and arylalkyl secondary alcohols such as 1-phenylethanol and benzhydrol were effectively hydrogenated to hydrocarbons (methylene) by NaBH₄, in combination with A1C1₃.

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Hydrogenation of Diaryl and Arylalkyl Ketones by Sodium Borohydride and Aluminum Chloride

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Hydrogenation of Diaryl and Arylalkyl Ketones by Sodium Borohydride and Aluminum Chloride

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