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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 19, 1989 - Issue 3-4
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Original Articles

Synthesis of Substituted Trans-1,6-Dimethylbicyclo[4.3.0]-non-2-enes Using A Claisen Rearrangement of α-(Thioalkoxy) Esters

Stewart K. Richardson Department of Chemistry, and Lucille Parker Markey Cancer Center, University of Kentucky, Lexington, KY, 40506
,
Mark R. Sabol Department of Chemistry, and Lucille Parker Markey Cancer Center, University of Kentucky, Lexington, KY, 40506
&
David S. Watt Department of Chemistry, and Lucille Parker Markey Cancer Center, University of Kentucky, Lexington, KY, 40506
Pages 359-367 | Received 27 Jun 1988, Published online: 23 Oct 2006
 
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Abstract

The Claisen rearrangement of α-(thioalkoxy)-esters provided access to substituted trans-1, 6-dimethylbicyclo[4.3.0]non-2-enes characteristic of the CD rings of the cucurbitanes.

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