Study of the Influence of Ultrasound and Aqueous Solvent on the Diels-Alder Reaction: The Case of Cyclopentadiene and Acetamidoacrylates

José Elguero Institute de Química Médica, C. S. I. C. Juan de la Cierva, 3, 28006, Madrid, Spain

Pilar Goya Institute de Química Médica, C. S. I. C. Juan de la Cierva, 3, 28006, Madrid, Spain

Juan Antonio Páez Institute de Química Médica, C. S. I. C. Juan de la Cierva, 3, 28006, Madrid, Spain

Carlos Cativiela Química Orgánica, Universidad de Zaragoza, Spain

José Antonio Mayoral Química Orgánica, Universidad de Zaragoza, Spain

Abstract

The influence of ultrasound and water, both separately and combined, on the Diels-Alder reaction between cyclopentadiene and methyl and benzyl-2-acetamidoacrylates has been studied. Ultrasonic irradiation does not improve the yield. Water is worse than toluene as solvent both in yield and in exo/endo selectivity.

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Study of the Influence of Ultrasound and Aqueous Solvent on the Diels-Alder Reaction: The Case of Cyclopentadiene and Acetamidoacrylates

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Study of the Influence of Ultrasound and Aqueous Solvent on the Diels-Alder Reaction: The Case of Cyclopentadiene and Acetamidoacrylates

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