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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 19, 1989 - Issue 3-4
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Original Articles

Synthesis of Thiiranes from Epoxides in the Presence of Thiourea in a Weakly Hydrated Organic Medium

H. Bouda Laboratoire de Chimie des Agroressources, Institut National Polytechnique, Ecole Nationale Supérieure de Chimie, 118 route de Narbonne, 31077, TOULOUSE Cédex, FRANCE
,
M. E. Borredon Laboratoire de Chimie des Agroressources, Institut National Polytechnique, Ecole Nationale Supérieure de Chimie, 118 route de Narbonne, 31077, TOULOUSE Cédex, FRANCE
,
M. Delmas Laboratoire de Chimie des Agroressources, Institut National Polytechnique, Ecole Nationale Supérieure de Chimie, 118 route de Narbonne, 31077, TOULOUSE Cédex, FRANCE
&
A. Gaset Laboratoire de Chimie des Agroressources, Institut National Polytechnique, Ecole Nationale Supérieure de Chimie, 118 route de Narbonne, 31077, TOULOUSE Cédex, FRANCE
Pages 491-500 | Received 30 Jun 1988, Published online: 23 Oct 2006
 
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Abstract

Reactivity of thiourea in the absence or in the presence of ethanol, towards several furanic, aromatic, aliphatic, and cyclic epoxides is studied. These results are compared to other ones obtained in the same conditions with another sulfured agent: KSCN.

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