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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 19, 1989 - Issue 5-6
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Original Articles

Stereocontrolled Conversion of 3,5-Dioxopyrrolizidine Into (Z)- and (E)- 5-Acetonylpyrrolizidin-3-ones

Kimio Takahashi Section on Medicinal Chemistry, Laboratory of Analytical Chemistry, NIDDK, National Institutes of Health, Bethesda, Maryland, 20892, U.S.A.
&
Arnold Brossi Section on Medicinal Chemistry, Laboratory of Analytical Chemistry, NIDDK, National Institutes of Health, Bethesda, Maryland, 20892, U.S.A.
Pages 835-841 | Received 12 Jul 1988, Published online: 24 Oct 2006
 
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Abstract

Stereocontrolled synthesis of (Z)-5-acetonyl-pyrrolizidin-3-one (4) and (E)-isomer 5 from 3,5-dioxopyrrolizidine 1 is described.

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