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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 19, 1989 - Issue 5-6
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Original Articles

Polymer-Supported Bases. 10. Synthesis of Phosphatidylcholines Using Polymer-Supported or Free Acylimidazoles

Masao Tomoi Department of Applied Chemistry, Faculty of Engineering, Yokohama National University, Yokohama, 240, Japan
,
Kiyoshi Inomata Department of Applied Chemistry, Faculty of Engineering, Yokohama National University, Yokohama, 240, Japan
,
Hiroshi Kakiuchi Department of Applied Chemistry, Faculty of Engineering, Yokohama National University, Yokohama, 240, Japan
&
Satoru Tokuyama Tsukuba Research Laboratory, Nippon Oil &Fats Co. Ltd., Ibaraki, 300-26, Japan
Pages 907-915 | Received 02 Sep 1988, Published online: 24 Oct 2006
 
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Abstract

Dipalmitoylphosphatidylcholine was synthesized in a good yield by the reaction of L-α-glycerophosphorylcholine with 1-palmitoylimidazole in the presence of DBU. Polymer-supported 1-palmitoylimidazole moiety also could be used as the acylating reagent, though the yield of the choline was moderate.

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