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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 19, 1989 - Issue 9-10
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Original Articles

A Practical Catalytic Procedure for Oxidation of Alcohols Into Aldehydes or Ketones with RuCl3/Water and Ca(OCl)2 or NaIO4

J. P. Genet Laboratoire de Chimie Organique et Organométallique, Université P. et M. Curie, 8, rue Cuvier, 75005, PARIS, France; Ecole Nationale Supérieure de Chimie, 11, rue Pierre et Marie Curie, 75005, Paris
,
D. Pons Laboratoire de Chimie Organique et Organométallique, Université P. et M. Curie, 8, rue Cuvier, 75005, PARIS, France
&
S. Jugé Laboratoire de Chimie Organique et Organométallique, Université P. et M. Curie, 8, rue Cuvier, 75005, PARIS, France
Pages 1721-1726 | Received 09 Jan 1989, Published online: 24 Oct 2006
 
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Abstract

Ruthenium complexes catalyze the oxidation of alcohols to the corresponding ketones or aldehydes when Ca(OCl)2 or NaIO4 are used as oxygen donors in the presence of water (5–10 equiv.). The reactions take place at room temperature affording products in yields of 45–80%.

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