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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 19, 1989 - Issue 9-10
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Original Articles

Enantioconvergent Synthesis of (-)-α-Cuparenone Involving Chiral Inversion of a Ketone Intermediate

Milind M. Gharpure National Chemical Laboratory, Pune, 411 008, India
&
A. S. Rao National Chemical Laboratory, Pune, 411 008, India
Pages 1813-1823 | Received 07 Dec 1988, Published online: 24 Oct 2006
 
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Abstract

The acid (-)-2 was converted to the ketone (-)-6. Unsaturated ketone (+)-14 was synthesised from (-)-6. The ketone (+)-7 prepared from the acid (+)-3 on 1,2-ketone transposition, furnished the optical antipode (-)-6.

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