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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 19, 1989 - Issue 11-12
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Original Articles

Direct Formation and Reaction of Functionalized thienyl-Based Organocopper Reagents

Reuben D. Rieke Department of Chemistry, University of Nebraska-Lincoln, Lincoln, Nebraska, 68588-0304
,
Tse-Chong Wu Department of Chemistry, University of Nebraska-Lincoln, Lincoln, Nebraska, 68588-0304
,
Dean E. Stinn Department of Chemistry, University of Nebraska-Lincoln, Lincoln, Nebraska, 68588-0304
&
Richard M. Wehmeyer Department of Chemistry, University of Nebraska-Lincoln, Lincoln, Nebraska, 68588-0304
Pages 1833-1840 | Received 14 Mar 1989, Published online: 24 Oct 2006
 
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Abstract

Highly reactive copper solutions have been prepared by the direct reduction of lithium 2-thienylcyanocuprate. Product isolation was much easier using the thienyl-based organocopper reagents as opposed to phosphine-based organocopper reagents.

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