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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 19, 1989 - Issue 11-12
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Original Articles

Recovery of Arenes Containing Keto or Ester Groups by the Electrochemical Reduction of Their Respective Cyclopentadienyliron Complexes

Alaa S. Abd-el-aziz Department of Chemistry, University of Saskatchewan, Saskatoon, Saskatchewan, S7N OWO, Canada; Department of Chemistry, University of Toronto, Toronto, Ontario, M5S 1A1, Canada
,
Adam Piórko Department of Chemistry, University of Saskatchewan, Saskatoon, Saskatchewan, S7N OWO, Canada
,
Andrzej S. Baranski Department of Chemistry, University of Saskatchewan, Saskatoon, Saskatchewan, S7N OWO, Canada
&
Ronald G. Sutherland Department of Chemistry, University of Saskatchewan, Saskatoon, Saskatchewan, S7N OWO, Canada
Pages 1865-1870 | Received 03 Feb 1989, Published online: 24 Oct 2006
 
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Abstract

Electrochemical reduction of the cyclopentadienyliron hexafluorophosphates of benzophenone, o-chlorophenyldibenzoylmethane and diethyl ethylphenylmalonate led to the liberation of arenes without reduction of keto or ester groups in over 85% yields.

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