New Synthesis of Diethyl Auylphosphonates and Diethyl Alkenylphosphonates

Kyeongho Chang Department of Chemistry, Korea Advanced Institute of Science & Technology, P.O. Box 150. Cheongyany-Ni, Seoul, 130-650, Korea

Bonchul Ku Department of Chemistry, Korea Advanced Institute of Science & Technology, P.O. Box 150. Cheongyany-Ni, Seoul, 130-650, Korea

Dong Young Oh Department of Chemistry, Korea Advanced Institute of Science & Technology, P.O. Box 150. Cheongyany-Ni, Seoul, 130-650, Korea

Abstract

Organometallic reagents readily added to diethyl l-(trimethylsilyl) vinylphosphonate 1 by virtue of the polarizing silyl group. Quenching with acetic acid, methyl iodide, and carbonyl compounds gave synthetically useful diethyl alkylphosphonates 6 and diethyl alkenylphosphonates 8 respectively.

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New Synthesis of Diethyl Auylphosphonates and Diethyl Alkenylphosphonates

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New Synthesis of Diethyl Auylphosphonates and Diethyl Alkenylphosphonates

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