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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 19, 1989 - Issue 11-12
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Original Articles

A Facile Reductive Cleavage of Allylic and Benzylic Esters with Low Valent Titanium Reagents

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Pages 2159-2166 | Received 17 Feb 1989, Published online: 24 Oct 2006
 

Abstract

The reductive cleavage of allylic and benaylic esters 1a-g with titanium(II) reagent derived from Mg/Hg-TiCl yielded the corresponding acids 3a-g and dimeric hydro 4 carbons 2a-g under mild reaction conditions.

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