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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 20, 1990 - Issue 20
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Original Articles

Reaction of Metal-Free Triorganogermyl Anions with Aldehydes

Mikio Kabaki Faculty of Pharmaceutical Sciences, Nagoya City University, Tanabe-dori, Mizuho-ku, Nagoya, 467, Japan
,
Sumie Inoue Faculty of Pharmaceutical Sciences, Nagoya City University, Tanabe-dori, Mizuho-ku, Nagoya, 467, Japan
,
Yoko Nagata Faculty of Pharmaceutical Sciences, Nagoya City University, Tanabe-dori, Mizuho-ku, Nagoya, 467, Japan
&
Yoshiro Sato Faculty of Pharmaceutical Sciences, Nagoya City University, Tanabe-dori, Mizuho-ku, Nagoya, 467, Japan
Pages 3245-3252 | Received 12 Sep 1990, Published online: 24 Oct 2006
 
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Abstract

Hexaorganosilylgermane (2) reacted with aldehydes and ketones (1) in the presence of catalytic amounts of fluoride ion in THF or HMPA to give 1-(triorgano-germyl)alkyl alcohols (3).

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